4 Types of PCB Contaminants and How to Remove Them

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Content Source: https://www.microcare.com/en-US/Resources/Insights/May-2022/4-Types-of-Contaminant-and-How-to-Remove-Them

Today’s electronic components are smaller and more complex than ever before. Manufacturers squeeze micro components like CSP, flip chip, micro BGA and QFN packages into tighter spaces on the PCBAs. Low standoff components like MOSFETs and zero-clearance components are now routine. As PCBAs continue to shrink in size and grow in density, cleaning them is more challenging. Dirty PCBAs are vulnerable to damaging parasitic leakage, electrochemical migration, delamination, shorting and dendrite growth. So, it’s important to know the type of contamination found on PCBAs and how to best remove it.

Four Types of Contamination

Depending the PCBAs are made, stored, or shipped, they can be exposed to uncured solder paste, fingerprint oils, marking inks, glues and conformal coatings as well as other ionics (a residue with conductive properties), organics and particulates that must be removed to allow the PCBAs to perform flawlessly.

There are four major types of PCBA contamination – organics, inorganics, water and insoluble particulate. Each one of these contaminants requires a different cleaning solution.

Organics:  Organic contaminants include rosin solder pastes and fluxes that come in grades of activation including R (Rosin), RA (Rosin Activated), RMA (Rosin Mildly Activated) and SA (Synthetic) and create bright, strong solder joints. The pastes and fluxes are typically a mix of solvents, resins and rheological additives. The resins are highly hygroscopic polar compounds or non-polar resins. Organic contaminants can also include non-polar oils and greases.  Organic contamination can be dissolved and removed with specialty cleaning fluids or flux removers. A mild to medium strength cleaning fluid or flux remover typically works best on organic contaminants.

Inorganics: Inorganics are usually flux and solder paste activators that include acids, bases and halogens. Inorganic contamination typically comes from the polar residue left by lead-free and no clean fluxes and solder pastes. The activators in these high-temperature reflow fluxes and solder pastes are commonly chlorides or corrosive salts, including plating salts. Inorganic contamination sometimes appears on PCBAs as white residue which can be extremely difficult to remove. Inorganic contaminants usually require more aggressive cleaning fluids to remove contaminants, especially the stubborn white residue. So, it’s important to test the chosen flux remover or cleaner prior to use to ensure it won’t damage the PCBA’s plastic components.

Water: Water is a subset of inorganic contamination and creates some special PCBA cleaning situations.  Some manufacturers clean PCBAs with water and dry them with air knives or heat. However, there is a chance that water could still be trapped in small areas on the boards, such as under tight-fitting PCBA components.

This water contamination can be removed from PCBAs using batch drying in a vapor degreaser outfitted with a water separator. There are two types of drying fluid methods available and which one to use depends on the quantity of water to be removed.

Absorption drying is best suited for removing small quantities of water. The drying fluid is a fluorinated solvent and alcohol mix. It is hydrophilic so it absorbs water off the PCBAs and prevents water spots from forming.

For very wet applications, displacement drying is the best option.  Displacement drying fluids contain a surfactant that moves water droplets off the surface of the PCBAs. The solvent used is hydrophobic or immiscible and is dense enough that it displaces the water on the PCBAs. The water floats to the surface of the drying fluid and is removed to properly dry the PCBA.

Particulate: Particulate is a polar contaminant that is commonly found on PCBAs. Particulate contamination is insoluble and cannot be dissolved in either water or a cleaning fluid. Particulate ranges in size from submicroscopic to large enough to be seen with the naked eye. As a general rule, the bigger the particulate, the more difficult it is to remove.  Some of the more common particulates found on PCBAs include dust, dirt, cloth fibers and metal chips.

Particulates bond electrostatically to PCBA surfaces and require an electrostatic polar cleaning fluid to break that bond. A dense cleaning fluid that contains slightly conductive molecules will break the static bond of the contaminant and displace, or float, the particulate off the PCBA substrate.

When removing insoluble contamination, adding agitation to the cleaning fluid is helpful. For benchtop cleaning, using the mechanical action of a brush helps scrub and dislodge the particulate from the PCBAs. For bulk cleaning, there are a number of methods to add agitation. Leveraging the boiling action of the cleaning fluid, adding vibrating ultrasonic energy or using a spray wand to help to loosen the particulate off the PCBA are all good ways to enhance the cleaning fluid’s effectiveness. 

Choosing a Cleaner

There is a vast array of PCBA cleaners and flux removers on the market, so it is important to choose one that cleans effectively and leaves no residue. It should also be fast drying to improve board cleaning time and also be materials compatible, generally plastic-safe, to prevent PCBA damage. It should be low odor and, if possible, nonflammable for worker safety. Also, don’t overlook price point, the cleaner or flux remover has to work within the budget. If using aerosol cans of cleaning fluid on the benchtop, perhaps consider using a controlled dispensing system like the MicroCare TriggerGrip Solvent Mister that attaches to the flux remover or cleaner can. This tool delivers faster and better cleaning, with less waste, driving down the overall cost-per-part cleaned.

Cleaning Trials

Although cleaner capability is important, so is its compatibility with the substrate being cleaned.  If you are unsure about the materials of the PCBA construction, it is important to test before the widespread deployment of a cleaner or flux remover.

A good method of ensuring the chosen PCBA cleaner or flux remover will work effectively without damaging a PCBA is to conduct a ‘cleaning trial’ on sacrificial or test boards. The best practice is to start with a milder cleaner first and progressively try stronger ones until the optimal cleaning result is achieved. It is recommended that tests be performed in more than one area on the PCBA to ensure it is safe for all the materials the cleaner may contact, either directly or indirectly. Microcare has field engineers who can provide guidance on testing the cleaning fluids and how to select the best one for the PCBA material and the specific contamination.

Explore the full line of MicroCare flux removers at Techni-Tool.com